Yes, not only can you get good results....you can get GREAT results using a video light as a hair light..or a rim light/backlight...etc.
And yes the color balance will be different...use that fact to your advantage.
The photo below (Playmate Audra Lynn) was taken with an old video light, and a simple (and cheap) halogen lamp and a studio strobe as the main light...though the "main" light in this case was actually used to fill her from the front.
There's 3 different sources of light here and all of them have a different color temperature.
Don't be afraid to break those rules!