I agree that #3 is the best shot... The only thing I would like to see there is a bit brighter catchlight. Everything else works well.
On the second the angle is real bad as it looks like she has a bald spot...
The first shot would be great if she would ge looking more towards camera. (down a bit and to her right) The other thing you could have done is to use a polarizer. You would have gotten deeper blues and better overall contrast. The colors would have popped a bit more as well.
You mention Photoshop. If you can try this.... If you shot in RAW then it's easy if not try opening the JPG in camera RAW and do the following.... Raise the exposure more than you normally would, on this shot a guess would be about a stop up. The ratchet up recovery to bring the blown highlights into range again. I bring it up as high as 60 or 70. Then raise the fill light a bit, to about 30. Last raise the blacks to boost contrast. Play with this a bit, settings will vary but play around.... This will give you a rich, bold, higher contrast look. If you tone it down to taste you might end up with a better look to the shot....
South Florida Photographer