Lots of ways to do it. One quick way I've used is to select the white part of the eyes, then desaturate to maybe -25 to -30, then add a touch of brightness back, like around 4 to 6. Be careful about over doing it though, it's really obvious if you add too much brightness back in. If done right, it just makes the little veins less noticable and leaves a realistic effect, rather than making the eyes perfectly white.
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