unless you are shooting strictly for the web why are you shooting sRGB?
You are throwing away a lot of color information before you get to Photoshop.
If you want to most of your color(largest color gamut) you should shoot Adobe RGB.
From Wikipedia...
"An RGB color space is any additive color space based on the RGB color model.
RGB is shorthand for Red, Green, Blue.
RGB is a convenient color model for computer graphics because the human visual system works in a way that is similar - though not quite identical - to an RGB color space. The most commonly used RGB color spaces are sRGB and Adobe RGB, which has a significantly larger gamut than sRGB. Adobe has recently developed another color space called Adobe Wide Gamut RGB, which is even larger, in detriment of gamut density.
As of 2004, sRGB is by far the most commonly used RGB color space, particularly in consumer grade digital cameras, because it is considered adequate for most consumer applications, and its design simplifies previewing on the typical computer display. Adobe RGB is also being built into more medium-range digital cameras, and is favored by many professional graphic artists.
RGB spaces are generally specified by defining three primary colors and a white point. In the table below the three primary colors and white points for various RGB spaces are given. The primary colors are specified in terms of their CIE chromaticity coordinates (x,y)."
whereas this does not address your original issue, it might help with your color.
Regards,
Stu
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